Photoelectrochemical reduction of CO2 in water under visible-light irradiation by a p-type InP photocathode modified with an electropolymerized ruthenium complex
Photoelectrochemical reduction of CO2 in water under visible-light irradiation by a p-type InP photocathode modified with an electropolymerized ruthenium complex
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DOI：
10.1039/c0cc02061c
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发表时间：
2010-10-07
影响因子：
4.9
通讯作者：
Motohiro, Tomoyoshi
中科院分区：
文献类型：
--
作者：
Arai, Takeo;Sato, Shunsuke;Motohiro, Tomoyoshi
利用电聚合钌配合物修饰的p型InP光电阴极成功实现了CO2的光电化学还原。该技术通过利用太阳能降低了CO2减排所需的应用潜力。HCOO-的碳源和质子源通过示踪实验确定为CO2和H2O。
Photoelectrochemical reduction of CO2 to HCOO- was successfully achieved by a p-type InP photocathode modified with an electropolymerized ruthenium complex in water. This technique decreased the required applied potential for CO2 reduction by utilizing solar energy. The carbon and proton sources of HCOO- were identified by a tracer experiment to be CO2 and H2O, respectively.