Sandwich complexes containing bent palladium chains.
Sandwich complexes containing bent palladium chains.
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DOI：
10.1002/anie.200601641
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发表时间：
2006-09
影响因子：
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通讯作者：
Yasuki Tatsumi;Katsunori Shirato;Tetsuro Murahashi;S. Ogoshi;H. Kurosawa
中科院分区：
文献类型：
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作者：
Yasuki Tatsumi;Katsunori Shirato;Tetsuro Murahashi;S. Ogoshi;H. Kurosawa
自1951年至1952年二茂铁的里程碑式发现以来，[1]有机金属夹心化合物由于其作为分子材料和催化剂的广泛用途而成为广泛研究的主题。[2]最近，我们发展了一维夹心链配合物作为一类新的扩展的有机金属夹心化合物。[3，4]已经证明，全反式、全s-反式共轭多烯用作线性钯链的模板配体（例如，
Since the landmark discovery of ferrocene in 1951–52,[1] organometallic sandwich compounds have been the subject of extensive research owing to the wide utility of these as molecular materials and catalysts.[2] Recently, we developed one-dimensional sandwich chain complexes as a new class of extended organometallic sandwich compounds.[3, 4] It has been proven that all-trans, all-s-trans conjugated polyenes serve as template ligands for a linear palladium chain (for example,