C-H activation/borylation/oxidation: A one-pot unified route to meta-substituted phenois bearing ortho-/para-directing groups
C-H activation/borylation/oxidation: A one-pot unified route to meta-substituted phenois bearing ortho-/para-directing groups
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DOI：
10.1021/ja0349857
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发表时间：
2003-07-02
影响因子：
15
通讯作者：
Smith, MR
中科院分区：
文献类型：
--
作者：
Maleczka, RE;Shi, F;Smith, MR
描述了一种高效的一锅C−H活化/硼化/氧化制备苯酚的方案。这种方法对于产生含有邻位/对位导向基团的间取代苯酚特别有吸引力，因为这种底物很难被其他苯酚合成所获得。
An efficient one-pot C−H activation/borylation/oxidation protocol for the preparation of phenols is described. This method is particularly attractive for the generation of meta-substituted phenols bearing ortho-/para-directing groups, as such substrates are difficult to access by other phenol syntheses.