Synthesis, structures, and magnetic properties of metal-organic polyhedra based on unprecedented {V7} isopolyoxometalate clusters.
Synthesis, structures, and magnetic properties of metal-organic polyhedra based on unprecedented {V7} isopolyoxometalate clusters.
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DOI：
10.1039/c6dt02764d
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发表时间：
2016-09
影响因子：
4
通讯作者：
Yuteng Zhang;Shuang-Bao Li;Xinlong Wang;Yaru Gong;Kuizhan Shao;Zhong-Min Su
中科院分区：
文献类型：
--
作者：
Yuteng Zhang;Shuang-Bao Li;Xinlong Wang;Yaru Gong;Kuizhan Shao;Zhong-Min Su
用溶剂热法合成了两种等结构的钒基金属有机多面体(VMOP-16和VMOP-17)，它们是由前所未有的{V7}异多金属氧簇和二羧酸配体构成的。据我们所知，{V7}第二个建筑单元是首次报道的，与已报道的钒基拖把相比，它具有最高的钒氧簇核。
Two isostructural vanadium-based metal-organic polyhedra (denoted as VMOP-16 and VMOP-17) were synthesized by a solvothermal method, which are built from unprecedented {V7} isopolyoxometalate clusters and dicarboxylate ligands. To our knowledge, the {V7} second building unit is reported for the first time and features the highest nuclearity of vanadium-oxygen clusters compared with reported vanadium-based MOPs.