Solubility of dichlorobis(triphenylphosphine)nickel(II) in supercritical carbon dioxide

Solubility of dichlorobis(triphenylphosphine)nickel(II) in supercritical carbon dioxide
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二氯双(三苯基膦)镍(II)在超临界二氧化碳中的溶解度

DOI:
10.1021/je9701689
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发表时间:
1998
影响因子:
--
通讯作者:
C. Erkey
C. Erkey
中科院分区:
工程技术3区
文献类型:
--
作者:
D. Palo;C. Erkey

文献摘要

被引文献

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用动态法测定了二氯双(三苯基膦)镍(II)在超临界二氧化碳中的溶解度。在(308、318和328)K和(10.8 ~ 27.9)MPa的压力范围内测定了溶解度等温线。在恒定温度下,溶解度随密度的增加而线性增加,在恒定密度下,溶解度随温度的增加而增加。
The solubility of dichlorobis(triphenylphosphine)nickel(II) in supercritical carbon dioxide was determined using a dynamic method. Solubility isotherms were obtained at (308, 318, and 328) K in the pressure range (10.8 to 27.9) MPa. Solubilities increased linearly with increasing density at constant temperature and increased with increasing temperature at constant density.