Synthesis of tetrasubstituted and functionalized enol ethers by E-selective olefination of esters with ynolates
Synthesis of tetrasubstituted and functionalized enol ethers by E-selective olefination of esters with ynolates
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DOI：
10.1021/ja0561082
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发表时间：
2006-02-01
影响因子：
15
通讯作者：
Shishido, K
中科院分区：
文献类型：
--
作者：
Shindo, M;Kita, T;Shishido, K
我们开发了酯羰基的e -选择性烯烃，得到四取代、功能化的烯烃，并通过醇化物将硫醇酯的C - S插入得到β-酮硫醇酯。
We have developed theE-selective olefination of ester carbonyls to afford tetrasubstituted, functionalized olefins and the C−S insertion of thiol esters to give β-keto thiol esters via ynolates.