All-inorganic cesium lead halide perovskite nanocrystals for photodetector applications

All-inorganic cesium lead halide perovskite nanocrystals for photodetector applications
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DOI:
10.1039/c5cc08643d
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发表时间:
2016-01-01
影响因子:
4.9
通讯作者:
Lee, Jong-Soo
Lee, Jong-Soo
中科院分区:
化学2区
文献类型:
--
作者:
Ramasamy, Parthiban;Lim, Da-Hye;Lee, Jong-Soo

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在此,我们描述了简单,快速和可重复的卤素离子交换反应在CsPbX 3(X = Cl,Br,I)纳米晶体(NC)在室温下。通过卤素离子浓度的简单调节,这些NC的光致发光可以在整个可见光区域(425-655 nm)内调谐。首次展示了基于完全无机CsPbI 3 NCs的光电探测器器件。光电探测器表现出良好的开/关光电流比为10(5)。
Herein, we describe simple, fast and reproducible halide ion exchange reactions in CsPbX3 (X = Cl, Br, I) nanocrystals (NCs) at room temperature. Through the simple adjustment of the halide ion concentration, the photoluminescence of these NCs can be tuned over the entire visible region (425-655 nm). Photodetector devices based on entirely inorganic CsPbI3 NCs are demonstrated for the first time. The photodetectors exhibited a good on/off photocurrent ratio of 10(5).