A spider hanging inside a carbon cage: off-center shift and pyramidalization of Sc3N clusters inside C84 and C86 fullerene cages

A spider hanging inside a carbon cage: off-center shift and pyramidalization of Sc3N clusters inside C84 and C86 fullerene cages
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悬挂在碳笼内的蜘蛛:C84 和 C86 富勒烯笼内 Sc3N 簇的偏心移位和金字塔化

DOI:
10.1039/d2qi01318e
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发表时间:
2022
期刊:
Inorganic Chemistry Frontier
影响因子:
--
通讯作者:
Chen Ning
Chen Ning
中科院分区:
其他
文献类型:
--
作者:
Fu Ze;Guo Min;Yao Yang-Rong;Meng Qingyu;Yan Yingjing;Wang Qin;Shen Yi;Chen Ning

文献摘要

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Structural analysis shows that, in Sc 3 N@ C s (51365)-C 84 and Sc 3 N@ D 3 (19)-C 86 , the Sc 3 N clusters are shifted to one side of the cages and unexpectedly pyramidalized inside the large cages of C 84 and C 86 , which resembles a spider attached to a web.