A new condensation reaction for the synthesis of carboxylic esters from nearly equimolar amounts of carboxylic acids and alcohols using 2-methyl-6-nitrobenzoic anhydride
A new condensation reaction for the synthesis of carboxylic esters from nearly equimolar amounts of carboxylic acids and alcohols using 2-methyl-6-nitrobenzoic anhydride
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DOI：
10.1246/cl.2002.286
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发表时间：
2002-03-05
影响因子：
1.6
通讯作者：
Kubota, M
中科院分区：
文献类型：
--
作者：
Shiina, I;Ibuka, R;Kubota, M
在催化量的4-（二甲氨基）吡啶存在下，用2-甲基-6-硝基苯甲酸酐与三乙胺反应，由等摩尔量的羧酸和醇以优异的产率和高的化学选择性得到各种羧酸酯。
Various carboxylic esters were obtained in excellent yields with high chemoselectivities from nearly equimolar amounts of carboxylic acids and alcohols using 2-methyl-6-nitrobenzoic anhydride with triethylamine in the presence of a catalytic amount of 4-(dimethylamino)pyridine.