Periodic mesoporous silica chloride (PMSCl) as an efficient and recyclable catalyst for the Pechmann reaction

Periodic mesoporous silica chloride (PMSCl) as an efficient and recyclable catalyst for the Pechmann reaction
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DOI:
10.1016/j.catcom.2011.05.019
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发表时间:
2011-09
影响因子:
3.7
通讯作者:
B. Karimi;Hesam Behzadnia
B. Karimi;Hesam Behzadnia
中科院分区:
化学3区
文献类型:
--
作者:
B. Karimi;Hesam Behzadnia

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报道了一种具有2D P6mm六方结构的周期性介孔氯化硅(PMSCl)作为一种高效的、可循环使用的催化剂,用于多种酚类化合物通过Pechmann反应合成相应的香豆素。反应在无溶剂条件下以良好至优异的产率进行。
Periodic mesoporous silica chloride (PMSCl) with 2D P6mm hexagonal structure which can be prepared by a simple procedure is reported to act as an efficient and recyclable catalyst for the conversion of a variety of phenols into their corresponding coumarins through Pechmann reaction. The reactions were conducted under solvent-free conditions in good to excellent yields.