Cyclometalation vs. Werner-type coordination of sterically enforced palladium(II)-1,3-bis(pyridyl-2-imino)isoindolines (Pd-BPIs)
Cyclometalation vs. Werner-type coordination of sterically enforced palladium(II)-1,3-bis(pyridyl-2-imino)isoindolines (Pd-BPIs)
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DOI:
10.1039/b700400a
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发表时间:
2007-01-01
影响因子:
4
通讯作者:
Kleeberg, Christian
中科院分区:
文献类型:
--
作者:
Broering, Martin;Kleeberg, Christian
The reaction of 1,3-bis(4,6-dimethylpyridyl-2-imino) isoindoline and palladium acetate in methanol selectively yields the expected acetato palladium N,N,N-chelate or a cyclometalated tetranuclear dimer depending on the stoichiometry of the reactants.