Cyclometalation vs. Werner-type coordination of sterically enforced palladium(II)-1,3-bis(pyridyl-2-imino)isoindolines (Pd-BPIs)

Cyclometalation vs. Werner-type coordination of sterically enforced palladium(II)-1,3-bis(pyridyl-2-imino)isoindolines (Pd-BPIs)
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DOI:
10.1039/b700400a
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发表时间:
2007-01-01
影响因子:
4
通讯作者:
Kleeberg, Christian
Kleeberg, Christian
中科院分区:
化学2区
文献类型:
--
作者:
Broering, Martin;Kleeberg, Christian

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1,3-双(4,6-二甲基吡啶基-2-亚氨基)异吲哚啉与乙酸钯在甲醇中的反应,根据反应物的化学计量,选择性地生成预期的乙酸钯N,N,N-螯合物或环化的四核二聚体。
The reaction of 1,3-bis(4,6-dimethylpyridyl-2-imino) isoindoline and palladium acetate in methanol selectively yields the expected acetato palladium N,N,N-chelate or a cyclometalated tetranuclear dimer depending on the stoichiometry of the reactants.