Synthesis and axial ligation behaviour of sterically hindered Zn(II)-porphyrin liquid crystals
Synthesis and axial ligation behaviour of sterically hindered Zn(II)-porphyrin liquid crystals
复制标题
DOI：
10.1016/j.tetlet.2006.09.085
复制
发表时间：
2006-11-13
影响因子：
1.8
通讯作者：
Varghese, B.
中科院分区：
文献类型：
--
作者：
Arunkumar, C.;Bhyrappa, P.;Varghese, B.
合成了一类新的低熔点液晶八烷氧基卟啉。它们的 Zn(II) 配合物对胺（不同形状和大小）表现出有趣的连接行为，这归因于卟啉两个面上的空间位阻或疏水口袋，如 Zn(II)-八丁氧基卟啉的晶体结构所证明的那样。 (c) 2006 Elsevier Ltd. 保留所有权利。
A new class of low melting liquid crystalline octaalkyloxyporphyrins have been synthesised. Their Zn(II)-complexes display an interesting ligation behaviour towards amines (of varying shapes and sizes), ascribed to the steric hindrance or hydrophobic pockets on both the faces of the porphryin as evidenced from the crystal structure of Zn(II)-octabutyloxyporphyrin. (c) 2006 Elsevier Ltd. All rights reserved.