Two three-dimensional 2p-3d-4f heterometallic frameworks featuring a Ln6Cu24Na12 cluster as a node.
Two three-dimensional 2p-3d-4f heterometallic frameworks featuring a Ln6Cu24Na12 cluster as a node.
复制标题
DOI：
10.1021/ic200077r
复制
发表时间：
2011-04
影响因子：
4.6
通讯作者：
G. Zhuang;Wen-xian Chen;Haixia Zhao;Xiang‐Jian Kong;L. Long;Rong-Bin Huang;Lan-Sun Zheng
中科院分区：
文献类型：
--
作者：
G. Zhuang;Wen-xian Chen;Haixia Zhao;Xiang‐Jian Kong;L. Long;Rong-Bin Huang;Lan-Sun Zheng
两个三维2 p-3d-4f异质金属框架，其特征在于纳米尺寸的Ln（6）Cu（24）Na（12）在微波辐射条件下，通过H（2）ANMA（H（2）ANMA = L-丙氨酸-N-单乙酸）、Cu（NO（3））（2）和Ln（NO（3））（3）的反应，得到了作为节点的（Ln = Gd，Dy）簇合物。（Ln = Gd用于1，Dy用于2）与去离子水中的NaOH反应。磁性研究表明，1具有亚铁磁性.电导率的测量表明，1的行为作为质子导体。
Two three-dimensional 2p-3d-4f heterometallic frameworks featuring a nanosized Ln(6)Cu(24)Na(12) (Ln = Gd, Dy) cluster as a node have been obtained under microwave irradiation conditions through the reaction of H(2)ANMA (H(2)ANMA = L-alanine-N-monoacetic acid), Cu(NO(3))(2), and Ln(NO(3))(3) (Ln = Gd for 1, Dy for 2) with NaOH in deionized water. Investigations on the magnetic properties show that 1 exhibits ferrimagnetic behavior. The electrical conductivity measurements reveal that 1 behaves as a proton conductor.