Hybrid Organic-Inorganic Rotaxanes, Including a Hetero-Hybrid [3]Rotaxane Featuring Two Distinct Heterometallic Rings and a Molecular Shuttle
Hybrid Organic-Inorganic Rotaxanes, Including a Hetero-Hybrid [3]Rotaxane Featuring Two Distinct Heterometallic Rings and a Molecular Shuttle
复制标题
杂化有机-无机轮烷，包括具有两个不同的异金属环和分子梭的异杂杂化[3]轮烷
DOI：
10.1002/ange.201805439
复制
发表时间：
2018
影响因子：
--
通讯作者：
Timco G
中科院分区：
文献类型：
--
作者：
Timco G
[2]和[3]报道了基于{Ti 7 M}环的杂化轮烷（M是三价金属，例如FeIII或GaIII）。NMR研究表明[2]轮烷可以作为分子穿梭，而EPR研究[3]轮烷显示超分子组装体的顺磁组分之间存在弱相互作用。
[2] and [3] hybrid rotaxanes are reported based on {Ti7M} rings (M is a trivalent metal such as FeIIIor GaIII). NMR studies show that [2]rotaxanes can act as molecular shuttles, while EPR studies of [3]rotaxanes show weak interactions between the paramagnetic components of the supramolecular assemblies.