Novel syntheses of three C30H12 bowl-shaped polycyclic aromatic hydrocarbons
Novel syntheses of three C30H12 bowl-shaped polycyclic aromatic hydrocarbons
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DOI：
10.1002/anie.199704061
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发表时间：
1997-03-03
期刊：
影响因子：
--
通讯作者：
Scott, LT
中科院分区：
文献类型：
--
作者：
Hagen, S;Bratcher, MS;Scott, LT
标题化合物是正常的多环芳烃和高度应变、封闭的多面体富勒烯之间缺失的链接。化合物（VII）的结构首次在小于C78的富勒烯中发现。热环脱氢制备（III）的最佳方法是通过C-Br键的均裂生成芳基自由基。
The title compounds are the missing links between the normal polycyclic aromatic hydrocarbons and the highly strained, closed polyhedral fullerenes. The structure of compound (VII), reported for the first time, is not found in fullerenes smaller than C78. The best approach to (III) by thermal cyclodehydrogenation is the controlled generation of aryl radicals by homolysis of C-Br bonds.