Thermodynamics of Molecules Strongly Coupled to the Vacuum Field
Thermodynamics of Molecules Strongly Coupled to the Vacuum Field
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DOI：
10.1002/anie.201301861
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发表时间：
2013-09-27
影响因子：
16.6
通讯作者：
Ebbesen, Thomas W.
中科院分区：
文献类型：
--
作者：
Canaguier-Durand, Antoine;Devaux, Eloise;Ebbesen, Thomas W.
对分子与真空场强耦合过程进行了热力学分析，首次确定了耦合过程的吉布斯自由能、焓和熵。热力学参数是拉比分裂和微观溶剂化的函数。这些结果为理解光分子强耦合提供了一个新的框架。
The thermodynamics of strong coupling between molecules and the vacuum field is analyzed and the Gibbs free energy, the enthalpy, and entropy of the coupling process are determined for the first time. The thermodynamic parameters are a function of the Rabi splitting and the microscopic solvation. The results provide a new framework for understanding light‐molecule strong coupling.