Direct synthesis of bicyclic guanidines through unprecedented palladium(II) catalysed diamination with copper chloride as oxidant
Direct synthesis of bicyclic guanidines through unprecedented palladium(II) catalysed diamination with copper chloride as oxidant
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DOI：
10.1039/b719479j
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发表时间：
2008-05-28
影响因子：
4.9
通讯作者：
Muniz, Kilian
中科院分区：
文献类型：
--
作者：
Hovelmann, Claas H.;Streuff, Jan;Muniz, Kilian
以氯化铜为氧化剂，钯催化的胍分子内转移反应可以完全选择性地高产率地得到双环胍。
Palladium catalysed intramolecular guanidine transfer to alkenes can be accomplished with copper chloride as the oxidant to give bicyclic guanidines with complete selectivity and in high yields.