Chiral Bis-phosphoramidites Based on Linked-BINOL for Rhodium-catalyzed 1,4-Addition of Arylboronic Acids to α,β-Unsaturated Carbonyl Compounds
Chiral Bis-phosphoramidites Based on Linked-BINOL for Rhodium-catalyzed 1,4-Addition of Arylboronic Acids to α,β-Unsaturated Carbonyl Compounds
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DOI：
10.1246/cl.2005.1224
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发表时间：
2005-07
影响因子：
1.6
通讯作者：
Yasunori Yamamoto;K. Kurihara;N. Sugishita;K. Oshita;Dongguo Piao;N. Miyaura
中科院分区：
文献类型：
--
作者：
Yasunori Yamamoto;K. Kurihara;N. Sugishita;K. Oshita;Dongguo Piao;N. Miyaura
由Shibasaki的联二醇和[Rh（nbd）2 ]BF 4合成的铑（I）配合物在室温下催化芳基硼酸与烯酮的不对称1，4-加成反应，对映选择性高达99. 8%ee.
Cationic rhodium(I) complex prepared from Shibasaki's linked-BINOL and [Rh(nbd) 2 ]BF 4 catalyzed asymmetric 1,4-addition of arylboronic acids to enones at room temperature with high enantioselectivities up to 99.8%ee.