Cu(II)/Cu(0)@UiO-66-NH2: base metal@MOFs as heterogeneous catalysts for olefin oxidation and reduction
Cu(II)/Cu(0)@UiO-66-NH2: base metal@MOFs as heterogeneous catalysts for olefin oxidation and reduction
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Cu(II)/Cu(0)@UiO-66-NH2：贱金属@MOFs作为烯烃氧化和还原的多相催化剂
DOI：
10.1039/c6cc06076e
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发表时间：
2016
期刊：
影响因子：
--
通讯作者：
Yu-Bin Dong
中科院分区：
文献类型：
--
作者：
Jian-Cheng Wang;Yu-Hong Hu;Gong-Jun Chen;Yu-Bin Dong
报道了Cu(II) @UiO-66-NH2(1)和Cu(0)@UiO-66-NH2(2)两种含铜MOF材料。在温和的条件下，它们分别可以作为烯烃氧化和加氢的高效非均相催化剂。苯乙烯在室温下完全加氢15分钟，产率定量。
Two copper-loaded MOF materials, namely Cu(II)@Ui-O-66-NH2 (1) and Cu(0)@UiO-66-NH2 (2), are reported. They can, respectively, serve as highly efficient heterogeneous catalysts for olefin oxidation and hydrogenation under mild conditions. Complete styrene hydrogenation occurs in 15 min at ambient temperature with quantitative yield.