The Role of Palladium Nanoparticles as Catalysts for Carbon–Carbon Coupling Reactions
The Role of Palladium Nanoparticles as Catalysts for Carbon–Carbon Coupling Reactions
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钯纳米粒子作为碳-碳偶联反应催化剂的作用
DOI：
10.1002/9783527621323.ch10
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发表时间：
2008
期刊：
影响因子：
--
通讯作者：
J. G. Vries
中科院分区：
文献类型：
--
作者：
L. Djakovitch;K. Köhler;J. G. Vries
本章包含标题为：介绍稳定的钯胶体和纳米颗粒赫克反应中的钯胶体其他 C-C 偶联反应中的钯胶体无配体钯催化剂无配体赫克反应无配体钯在其他 C-C 键形成反应中作为催化剂的钯环、钳子和其他钯配合物钯纳米簇前体固体负载钯作为碳-碳偶联反应的催化剂负载型（固体）钯催化剂的赫克偶联 - 一般动机固体负载钯催化的赫克反应进展 - 溴苯和芳基氯化物的活化非活化芳基溴化物的赫克反应芳基的反应氯化物文献报告的结论催化剂的性质反应条件的重要性实际应用的潜力其他偶联反应中的负载型钯催化剂（负载型）纳米颗粒的赫克（及相关）反应的机理方面：均相还是非均相催化？机械循环结论
This chapter contains sections titled:IntroductionStable Palladium Colloids and NanoparticlesPalladium Colloids in the Heck ReactionPalladium Colloids in Other C‐C Coupling ReactionsLigand‐free Palladium CatalystsThe Ligand‐free Heck ReactionLigand‐free Palladium as Catalyst in Other C‐C Bond Forming ReactionsPalladacycles, Pincers and Other Palladium Complexes as Precursors of Palladium NanoclustersPalladium Supported on Solids as Catalysts for Carbon–Carbon Coupling ReactionsHeck Coupling by Supported (Solid) Pd Catalysts – General MotivationProgress in Heck Reactions Catalyzed by Palladium Supported on Solids – Activation of Bromobenzene and Aryl ChloridesHeck Reactions of Non‐activated Aryl BromidesReactions of Aryl ChloridesConclusions from the Literature ReportsProperties of the CatalystImportance of Reaction ConditionsPotential for Practical ApplicationsSupported Palladium Catalysts in Other Coupling ReactionsMechanistic Aspects of Heck (and Related) Reactions by (Supported) Nanoparticles: Homogeneous or Heterogeneous Catalysis?Mechanistic CycleConclusions