STOCHASTIC DYNAMICS IN IRREVERSIBLE NONEQUILIBRIUM ENVIRONMENTS. 2. A MODEL FOR THERMOSETTING POLYMERIZATION
STOCHASTIC DYNAMICS IN IRREVERSIBLE NONEQUILIBRIUM ENVIRONMENTS. 2. A MODEL FOR THERMOSETTING POLYMERIZATION
复制标题
不可逆非平衡环境中的随机动力学。
DOI：
10.1021/jp9836269
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发表时间：
1999
影响因子：
3.3
通讯作者：
F. Somer
中科院分区：
文献类型：
--
作者：
R. Hernandez;F. Somer
广义朗之万方程(GLE)的推广，即所谓的不可逆GLE(IGLE)[Hernandez，R.；Somer，F.L.J.Phys.化学。1999,103,1064]，进一步扩展到描述非平稳环境，其中非平稳是由系综本身的宏观行为引起的，而不是由外力引起的。这种形式主义有助于动态研究生长聚合物的长度分布。
A generalization of the generalized Langevin equation (GLE), the so-called irreversible GLE (iGLE) [Hernandez, R.; Somer, F. L. J. Phys. Chem. 1999, 103, 1064], is further extended to describe non-stationary environments in which the non-stationarity is induced by the macroscopic behavior of the ensemble itself, rather than an external force. Such a formalism lends itself to the dynamical study of the length distributions of growing polymers.