Synthesis of oxy aminated [60] and [70]fullerenes with cumene hydroperoxide as oxidant
Synthesis of oxy aminated [60] and [70]fullerenes with cumene hydroperoxide as oxidant
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DOI：
10.1246/cl.2007.20
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发表时间：
2007-01-05
影响因子：
1.6
通讯作者：
Nakamura, Eiichi
中科院分区：
文献类型：
--
作者：
Lemiegre, Loic;Tanaka, Takatsugu;Nakamura, Eiichi
用过量的仲胺和3等量的异丙苯氢过氧化物区选择性地处理[60]或[70]富勒烯，可获得高产好的单氧四氨基或二氨基富勒烯。该反应操作简单，适用于大规模合成。
Treatment of [60] or [70]fullerene with excess secondary amine and 3 equiv. of cumene hydroperoxide regioselectively afforded a mono-oxygenated tetraamino or diamino fullerene in good to high yield. The reaction is operationally simple and applicable to a large-scale synthesis.