Synthesis of new α,α′,β-trisubstituted β-lactones as monomers for hydrolyzable polyesters
Synthesis of new α,α′,β-trisubstituted β-lactones as monomers for hydrolyzable polyesters
复制标题
DOI:
10.1163/156855503771816822
复制
发表时间:
2003-01-01
影响因子:
1.6
通讯作者:
Guérin, P
中科院分区:
文献类型:
--
作者:
Barbaud, C;Abdillah, F;Guérin, P
Novel alpha,alpha',beta-trisubstitute beta-lactones have been prepared by a concise and efficient synthesis in five steps from commercial racemic diethyl oxalpropionate. These lactones with different lateral groups can be polymerized or co-polymerized for obtaining polyesters with high molecular weight. Chemical modification of these functionalized hydrolyzable polymers will be used to adjust their properties to the selected temporary applications.