Synthesis of new α,α′,β-trisubstituted β-lactones as monomers for hydrolyzable polyesters

Synthesis of new α,α′,β-trisubstituted β-lactones as monomers for hydrolyzable polyesters
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DOI:
10.1163/156855503771816822
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发表时间:
2003-01-01
影响因子:
1.6
通讯作者:
Guérin, P
Guérin, P
中科院分区:
化学4区
文献类型:
--
作者:
Barbaud, C;Abdillah, F;Guérin, P

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Novel alpha,alpha',beta-trisubstitute beta-lactones have been prepared by a concise and efficient synthesis in five steps from commercial racemic diethyl oxalpropionate. These lactones with different lateral groups can be polymerized or co-polymerized for obtaining polyesters with high molecular weight. Chemical modification of these functionalized hydrolyzable polymers will be used to adjust their properties to the selected temporary applications.