COUNTERION INDUCED PROCESSIBILITY OF CONDUCTING POLYANILINE
COUNTERION INDUCED PROCESSIBILITY OF CONDUCTING POLYANILINE
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DOI：
10.1016/0379-6779(93)90468-c
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发表时间：
1993-04-12
期刊：
影响因子：
4.4
通讯作者：
HEEGER, AJ
中科院分区：
文献类型：
--
作者：
CAO, Y;SMITH, P;HEEGER, AJ
通过对聚苯胺（聚苯胺的碱形式）使用适当官能化的酸，抗衡离子可以诱导所得PANI络合物的可加工性。因此，聚苯胺可以以导电形式从熔体和/或从各种常见有机溶剂（例如十氢化萘、二甲苯、氯仿和间甲酚等）加工。所得导电聚苯胺可以纯加工或与常见的绝缘本体聚合物共混，以能够制造薄膜、片材、纤维、透明导电膜、本体部件等。这些材料在聚苯胺络合物的低体积分数下表现出相对高水平的导电性，同时保持优异的机械性能。基本上等于主体本体聚合物的那些。
By using a suitably functionalized acid to polyaniline, the base form of polyaniline, the counter ion can induce processibility of the resulting PANI complex. Thus, polyaniline can be processed in its conducting form from the melt and/or from a wide variety of common organic solvents, such as decalin, xylene, chloroform and m-cresol, etc. The resulting conducting polyaniline can be processed neat or in blends with common, insulating bulk polymers to enable the fabrication of thin films, sheets, fibers, transparent conductive films, bulk parts, etc. These materials exhibit relatively high levels of electrical conductivity at low volume fractions of the polyaniline complex, while maintaining excellent mechanical properties. essentially equivalent to those of the host bulk polymer.