Low-molecular-mass metabolites of fungi. I. Stachybotrin from Stachybotrys alternans.
Low-molecular-mass metabolites of fungi. I. Stachybotrin from Stachybotrys alternans.
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DOI：
10.1007/bf02282366
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发表时间：
1997-01-01
影响因子：
0.8
通讯作者：
Isaev, M. I.
中科院分区：
文献类型：
--
作者：
Kamalov, L. S.;Aripova, S. F.;Isaev, M. I.
用柱层析法从水苏中分离得到含氮化合物水苏甙。alternans [S. atra]。根据化学转化以及1H和13 C NMR光谱、2 M NMR 1H-1H和1H-13 C化学位移相关（COSY）、长程1H-13 C相互作用相关（HMBC）、旋转坐标系中NOE测量（ROESY）以及IR和电子轰击质谱的结果确定了水苏碱的结构。
Using column chromatography, the nitrogen-containing compound stachybotrin was isolated from S. alternans [S. atra]. The structure of stachybotrin was determined on the basis of chemical transformations together with the results of 1H and 13C NMR spectroscopy, 2M NMR 1H-1H and 1H-13C chemical shift correlation (COSY), correlation of long-range 1H-13C interactions (HMBC), measurements of NOEs in a rotating coordinate system (ROESY), and IR and electron-impact mass spectra.