Controlling molecular and supramolecular structure of hydrogen-bonded coordination compounds
Controlling molecular and supramolecular structure of hydrogen-bonded coordination compounds
复制标题
控制氢键配位化合物的分子和超分子结构
作者：
C. Aakeröy;J. Desper;J. Valdés
为了组织和组装成无限的一维链所需的连接的八面体配合物，二苯甲酰基甲烷被用作螯合，“阻断”配体，和异烟酰胺和4-（3-carboxamidophenyl）吡啶被用作结构导向超分子试剂。五M（II）配合物的制备使用这种分子/超分子合成策略。这些化合物的晶体结构测定显示出相同的主要超分子基序;无限的1-D链。此外，DBM中相对庞大的苯基基团的存在降低了该系统中的填充效率，并为溶剂化主体结构的构建提供了更好的机会。
In order to organize and assemble a variety of octahedral coordination complexes into infinite 1-D chains of desired connectivity, dibenzoylmethane was used as a chelating, “blocking” ligand, and isonicotinamide and 4-(3-carboxamidophenyl)pyridine were employed as structure directing supramolecular reagents. Five M(II) complexes were prepared using this molecular/supramolecular synthetic strategy. The crystal structure determination of these compounds shows the same principal supramolecular motif; infinite 1-D chains. In addition, the presence of the relatively bulky phenyl groups in DBM reduces packing efficiency in this system and provides better opportunities for the construction of solvated host structures.
影响因子：
56.9
作者：
通讯作者：
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