Tetrahedral distortion in palladium(II) macrocyclic complexes: the single crystal X-ray structure of [Pd(tbc)](PF6)2·0.4MeNO2(tbc = 1,4,8,11-tetra-azacyclotetradecane)
Tetrahedral distortion in palladium(II) macrocyclic complexes: the single crystal X-ray structure of [Pd(tbc)](PF6)2·0.4MeNO2(tbc = 1,4,8,11-tetra-azacyclotetradecane)
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钯(II)大环配合物的四面体畸变：[Pd(tbc)](PF6)2·0.4MeNO2(tbc = 1,4,8,11-四氮杂环十四烷)的单晶X射线结构
DOI：
10.1039/c39870001730
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发表时间：
1987
期刊：
影响因子：
--
通讯作者：
M. Schröder
中科院分区：
文献类型：
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作者：
A. Blake;R. Gould;T. Hyde;M. Schröder
[Pd(tbc)](PF6)2·0.4MeNO2的单晶x射线结构在PdII周围呈现四面体畸变的方平面立体化学；这种畸变解释了PdII/PdI氧化还原对阳离子的阳极位移。
The single crystal X-ray structure of [Pd(tbc)](PF6)2·0.4MeNO2 shows a tetrahedrally distorted square-planar stereochemistry around PdII; this distortion accounts for the anodic shift of the PdII/PdI redox couple for the cation.