Pd-Catalyzed kinetic resolution of cyclic enol ethers. An enantioselective route to functionalised pyrans.
Pd-Catalyzed kinetic resolution of cyclic enol ethers. An enantioselective route to functionalised pyrans.
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DOI：
10.1039/c4cc00109e
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发表时间：
2014-02
影响因子：
4.9
通讯作者：
Jean-Olivier Zirimwabagabo;J. Harrity
中科院分区：
文献类型：
--
作者：
Jean-Olivier Zirimwabagabo;J. Harrity
在不对称催化[1，3]-重排反应后，官能化的环烯醇醚可以以高水平的对映体控制回收。这些化合物可以进一步加工成一系列碳和杂环产物，产率高，立体控制水平优异。
Functionalised cyclic enol ethers can be recovered with high levels of enantiocontrol after an asymmetric catalytic [1,3]-rearrangement reaction. These compounds can be further elaborated to a series of carbo- and heterocyclic products in good yield and with excellent levels of stereocontrol.