Hydration of sodium cobalt oxide
Hydration of sodium cobalt oxide
复制标题
DOI：
10.1021/cm0714786
复制
发表时间：
2007-12-11
影响因子：
8.6
通讯作者：
Takayama-Muromachi, Eiji
中科院分区：
文献类型：
--
作者：
Sakurai, Hiroya;Osada, Minoru;Takayama-Muromachi, Eiji
结果表明，NaxCoO2中的Na+离子可以被h30 +离子部分取代，同时保持Co价不变。Na- X (h30o)(z)CoO2的磁化率（X + z = 0.70）由居里-魏斯型转变为泡利顺磁性，表明电子能带结构被Na+/ h30o +的等价离子取代所修饰。讨论了电子结构变化的两种可能的来源。
It was found that Na+ ions in NaxCoO2 can be partially substituted by H3O+ ions while maintaining a constant Co valence simply by immersion in water. The Magnetic Susceptibility of Na-x(H3O)(z)CoO2 (X + z = 0.70) changed drastically from Curie-Weiss type to Pauli paramagnetic type, indicating that the electronic band structure was modified by the isovalent ion substitution of Na+/H3O+. Two possible origins of the change in the electronic structure are discussed.