Nickel-catalyzed reductive cleavage of aryl-oxygen bonds in alkoxy- and pivaloxyarenes using hydrosilanes as a mild reducing agent
Nickel-catalyzed reductive cleavage of aryl-oxygen bonds in alkoxy- and pivaloxyarenes using hydrosilanes as a mild reducing agent
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DOI：
10.1039/c0cc05169a
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发表时间：
2011-01-01
影响因子：
4.9
通讯作者：
Chatani, Naoto
中科院分区：
文献类型：
--
作者：
Tobisu, Mamoru;Yamakawa, Ken;Chatani, Naoto
研究了一种镍催化芳基烷基醚和芳基戊酸酯的还原脱氧反应。氢硅烷是一种温和的还原剂。目前的协议允许在芳烃官能化反应中使用私有基团作为稳健且无迹可寻的指导基团。
A nickel-catalyzed reductive deoxygenation of aryl alkyl ethers and aryl pivalates has been developed. Hydrosilanes serve as a mild reducing agent. The present protocol allows the use of a pivalate group as a robust and traceless steering group in arene functionalization reactions.