Palladium-catalyzed regio- and enantio-selective allylic substitution reaction of monosubstituted allyl substrates with benzyl alcohols

Palladium-catalyzed regio- and enantio-selective allylic substitution reaction of monosubstituted allyl substrates with benzyl alcohols
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钯催化单取代烯丙基底物与苯甲醇的区域和对映选择性烯丙基取代反应

DOI:
10.1016/j.tetasy.2010.03.045
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发表时间:
2010-05-17
影响因子:
--
通讯作者:
Dai, Li-Xin
Dai, Li-Xin
中科院分区:
其他
文献类型:
--
作者:
Fang, Ping;Ding, Chang-Hua;Dai, Li-Xin

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在钯催化的单取代烯丙基底物与取代苯甲醇的烯丙基取代反应中实现了区域选择性和对映选择性,得到了高区域选择性(高达93/7)和高对映选择性(高达96%)的相应产物。(C)2010爱思唯尔有限公司版权所有。
Regio- and enantio-selectivities in Pd-catalyzed allylic substitution reaction of monosubstituted allylic substrates with substituted benzyl alcohols were realized, affording the corresponding products in high regioselectivity (up to 93/7) and enantioselectivity (up to 96%). (C) 2010 Elsevier Ltd. All rights reserved.