Synthesis and structure of [NMe4][CuPt(CN)4]: an infinite three-dimensional framework related to PtS which generates intersecting hexagonal channels of large cross section

Synthesis and structure of [NMe4][CuPt(CN)4]: an infinite three-dimensional framework related to PtS which generates intersecting hexagonal channels of large cross section
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DOI:
10.1039/c39900000762
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发表时间:
1990
期刊:
Journal of The Chemical Society, Chemical Communications
影响因子:
--
通讯作者:
R. Gable;B. F. Hoskins;R. Robson
R. Gable;B. F. Hoskins;R. Robson
中科院分区:
其他
文献类型:
--
作者:
R. Gable;B. F. Hoskins;R. Robson

文献摘要

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[NMe 4][CuPt(CN)4]含有与PtS结构相关的无限3D [CuIPtII(CN)4]nn-骨架,其产生两组相互垂直且等效的大横截面的六边形通道(最大Pt/Pt对角线,13.50 A)以及垂直于六边形通道的大的空正方形通道。
[NMe4][CuPt(CN)4] contains an infinite 3D [CuIPtII(CN)4]nn– framework related to the PtS structure, which generates two mutually perpendicular and equivalent sets of hexagonal channels of large cross-section (largest Pt ⋯ Pt diagonal, 13.50 A) together with large empty square channels perpendicular to the hexagonal channels.