ROYAL PURPLE-DYE - THE CHEMICAL RECONSTRUCTION OF THE ANCIENT MEDITERRANEAN INDUSTRY
ROYAL PURPLE-DYE - THE CHEMICAL RECONSTRUCTION OF THE ANCIENT MEDITERRANEAN INDUSTRY
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DOI：
10.1021/ar00173a006
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发表时间：
1990-05-01
影响因子：
18.3
通讯作者：
MICHEL, RH
中科院分区：
文献类型：
--
作者：
MCGOVERN, PE;MICHEL, RH
图1.从软体动物腺分泌物的前体开始，靛蓝染料的化学合成途径。a为图2。主要的地中海软体动物物种，产生6，6 '-二溴靛蓝（DBI）和相关的靛蓝类：（a）M。truncuius;（B）M. brandaris;和（c）血口肺吸虫。转载自Besnier，M.《希腊和罗马古董词典》; Daremberg，C.，Saglio，E.，编辑;阿歇特：巴黎，1877-1919;第4卷，第770页，图5887。需要生产1克染料。4 5-6软体动物分布于世界各地，包括地中海、太平洋和大西洋，而且各种物种的染料前体的化学性质在许多方面都是相似的。4由于软体动物是一种常见的食物来源，分泌物的不寻常和强烈的颜色以及它们对染色的适应性很容易被发现。
Figure 1. Chemical pathways for the production of indigoid dyes, beginning with the precursors of the molluscan glandular se-cretions. a be Figure 2. Principal Mediterranean molluscan species, yielding 6, 6'-dibromoindigotin (DBI) and related indigoids:(a) M. truncuius;(b) M. brandaris; and (c) P. haemastoma. Reprinted from Besnier, M. Dictionnaire des antiquites grecques et romaines; Daremberg, C., Saglio, E., Eds.; Hachette: Paris, 1877-1919; Vol. 4, p 770, Fig. 5887. needed to produce 1 g of the dye. 4 5-6 The mollusks occur worldwide, including the Medi-terranean Sea and the Pacific and Atlantic Oceans, and the chemistry of the dye precursors has been shown to be similar in many respects for the various species. 4 Since the mollusks were a common food source, the unusual and intense coloration of the secretions and their suitability fordyeing would have been readily