Photochemical electron transfer in liquid/liquid solvent systems
Photochemical electron transfer in liquid/liquid solvent systems
复制标题
液/液溶剂体系中的光化学电子转移
DOI：
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发表时间：
1989
期刊：
影响因子：
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通讯作者：
M. Armond
中科院分区：
文献类型：
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作者：
V. Mareček;A. H. D. Armond;M. Armond
研究了溶于有机相中的光氧化还原电对钌-三联吡啶配合物Ru（byp）{sub 3}{sup 2+}和溶于水相中的甲基紫精MV{sup 2 +}在水/1，2-二氯乙烷和水/苯甲腈界面的光诱导电荷转移.得出的结论是，所观察到的光电流可以归因于激发钌络合物和甲基紫精之间的电子转移。
A photoinduced charge transfer at the water/1,2-dichloroethane and water/benzonitrile interfaces was studied, using the photoredox couple ruthenium-trisbipyridine complex, Ru(byp){sub 3}{sup 2+}, dissolved in the organic phase and methyl viologen, MV{sup 2+}, in the aqueous phase. It was concluded that the photocurrent observed can be ascribed to an electron transfer between the excited ruthenium complex and methyl viologen.