Advances in electro-copolymerization of NIR emitting and electronically conducting block copolymers
Advances in electro-copolymerization of NIR emitting and electronically conducting block copolymers
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DOI：
10.1039/c8tc06331a
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发表时间：
2019-03-21
影响因子：
6.4
通讯作者：
Watkins, Davita L.
中科院分区：
文献类型：
--
作者：
Rajapakse, R. M. Gamini;Attanayake, Nuwan H.;Watkins, Davita L.
包含苯并噻二唑的嵌段共聚物被成功地电共聚合，得到（BTD-T-2）（n）（BTD-F-2）（m），其中n和m以完全可控的、明确定义的方式变化。用循环伏安法、交流阻抗法、SEM-EDAX和XPS对聚合物进行了表征。它们在近红外（NIR）区域表现出吸收和发射。结果支持一种有效的策略，以创造更复杂的材料，在光电领域有无数可能的应用。
Block copolymers comprising benzothiadiazole were successfully electro-copolymerized leading to (BTD-T-2)(n)(BTD-F-2)(m), where n and m were varied in a perfectly controllable, well-defined manner. The polymers were characterized by cyclic voltammetry, AC-impedance, SEM-EDAX and XPS analyses. They exhibit absorbance and emission in the near infrared (NIR) region. Results support an efficient strategy towards the creation of even more complex materials with innumerable possible applications in optoelectronic.