Highly Phosphorescent Crystals of Vaulted trans-Bis(salicylaldiminato)platinum(II) Complexes
Highly Phosphorescent Crystals of Vaulted trans-Bis(salicylaldiminato)platinum(II) Complexes
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DOI：
10.1021/ja110398p
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发表时间：
2011-05-04
影响因子：
15
通讯作者：
Naota, Takeshi
中科院分区：
文献类型：
--
作者：
Komiya, Naruyoshi;Okada, Minoru;Naota, Takeshi
新合成的各种反式双(水杨醛缩合)铂(II)配合物作为已有研究的双(水杨醛缩合)配合物的第三配位模式，在晶态下观察到了前所未有的强磷光发射。这篇通讯描述了这些配合物在液态和晶态下的动态光物理性质，以及在晶态下强发射的机理基础。
Unprecedented strong phosphorescent emission in the crystalline state is observed for a variety of vaulted trans-bis(salicylaldiminato)platinum(II) complexes which are newly synthesized as a third coordination mode of well-studied bis(salicylaldiminato) complexes. This Communication describes the dynamic photophysical properties of these complexes in the liquid and crystalline states and a mechanistic rationale for the strong emission in the crystalline state.