Purification and characterization of phthalocyanines
Purification and characterization of phthalocyanines
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DOI：
10.1007/bf00644652
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发表时间：
1982-10
影响因子：
4.5
通讯作者：
H. Wagner;R. Loutfy;C. Hsiao
中科院分区：
文献类型：
--
作者：
H. Wagner;R. Loutfy;C. Hsiao
给出了一种简单的用于有机物提纯的列车升华(载气)系统的技术细节，并描述了提纯过程。采用光吸收、X-射线衍射、电子顺磁共振、升华行为和光伏数据等手段，研究了不含金属的酞菁(H_2Pc)、镁酞菁(MgPc)、铜酞菁(CuPc)、钒基酞菁(VOPc)、锌酞菁(ZnPc)和铅酞菁(PbPc)的提纯效果。结果表明，菌丝升华显著提高了颜料的质量。光谱结果表明，在提纯的镁碳化物中存在第二相。
The technical details of a simple train sublimation (carrier gas) system for purification of organic materials are given and the refining procedure is described. A study of the effects of purification on metal free phthalocyanine (H2Pc), magnesium phthalocyanine (MgPc), copper phthalocyanine (CuPc), vanadyl phthalocyanine (VOPc), zinc phthalocyanine (ZnPc) and lead phthalocyanine (PbPc) was carried out by means of optical absorption, X-ray diffraction, electron paramagnetic resonance, sublimation behaviour and photovoltaic data. It was found that train sublimation improves the quality of the pigments considerably. Spectroscopic results indicate the presence of a second phase in the purified MgPc.