InCl3-Catalyzed Alkylation of Aromatic and Heteroaromatic Compounds with Cyclic Allylic Acetates

InCl3-Catalyzed Alkylation of Aromatic and Heteroaromatic Compounds with Cyclic Allylic Acetates
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InCl3 催化芳香族和杂芳香族化合物与环状烯丙乙酸酯的烷基化

DOI:
10.1055/s-2006-958418
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发表时间:
2006
期刊:
影响因子:
2
通讯作者:
B. Jagadeesh
B. Jagadeesh
中科院分区:
化学4区
文献类型:
--
作者:
J. Yadav;B. Reddy;K. V. Rao;P. P. Rao;K. Raj;A. Prasad;A. Prabhakar;B. Jagadeesh

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各种芳香族和杂芳族化合物与环烯丙基乙酸酯在10mol%的三氯化铟存在下在温和的条件下进行光滑的烷基化反应,得到3-取代吲哚、2-取代呋喃、吡咯和环己烯取代芳烃,产率高,选择性高。
Various aromatic and heteroaromatic compounds undergo smooth alkylation with cyclic allylic acetates in the presence of 10 mol% of indium trichloride under mild conditions to afford 3-substituted indoles, 2-substituted furan and pyrrole and cyclohexenyl-substituted arenes in good yields with high selectivity.