Straightforward access to aryl-substituted/fused 1,3-dithiole-2-chalcogenones by Cu-catalyzed C-S coupling between aryl iodides and zinc-thiolate complex (TBA)2[Zn(DMIT)2]
Straightforward access to aryl-substituted/fused 1,3-dithiole-2-chalcogenones by Cu-catalyzed C-S coupling between aryl iodides and zinc-thiolate complex (TBA)2[Zn(DMIT)2]
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DOI：
10.1039/c3ra41349g
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发表时间：
2013-01-01
期刊：
影响因子：
3.9
通讯作者：
Shao, Xiangfeng
中科院分区：
文献类型：
--
作者：
Sun, Jibin;Lu, Xiaofeng;Shao, Xiangfeng
实现了碘芳基和硫醇锌络合物之间的铜催化 C-S 偶联。该方案为芳基取代/稠合 1,3-二硫醇-2-硫属元素酮提供了一种简便有效的合成方法，可将其转化为 TTF。
The Cu-catalyzed C-S coupling between iodoaryl and a zincthiolate complex was achieved. This protocol provides a facile and efficient synthetic approach for aryl-substituted/fused 1,3-dithiole-2-chalcogenones, which can be converted to TTFs.