Structures and Ionization Energies of Sandwich Clusters (Vn(benzene)m)
Structures and Ionization Energies of Sandwich Clusters (Vn(benzene)m)
复制标题
DOI：
10.1021/j100010a013
复制
发表时间：
1995
期刊：
影响因子：
--
通讯作者：
K. Hoshino;T. Kurikawa;H. Takeda;A. Nakajima;K. Kaya
中科院分区：
文献类型：
--
作者：
K. Hoshino;T. Kurikawa;H. Takeda;A. Nakajima;K. Kaya
自从通过激光蒸发金属棒合成金属团簇的发展以来，在分子束条件下研究了各种过渡金属团簇，这些过渡金属团簇由于它们的高沸点温度而不能通过坩埚方法产生。有几个研究小组通过改进激光蒸发方法，在气相中成功地合成了金属分子络合物。1-7近年来，邓肯等和Preiser等报道了金属离子-苯配合物的光致裂解过程，研究了金属离子-苯配合物的光致裂解过程。8· 9 Armentrout及其同事在碰撞诱导碎裂实验中测定了金属离子-苯络合物的结合能。10大部分
Since the development of the synthesis of metal clusters by laser vaporization of the metal rod, variouskinds of transitionmetal clusters which cannot be produced by a crucible method because of their high boiling temperatures have been studied under molecular beam conditions. Several groups independently have succeeded in thesynthesis of metal—molecule complexes in the gas phase by modifying the laser vaporization method. 1-7 Metal—molecule complexes in the gas phase have been studied in orderto investigate the interaction between the metalatom and ligand molecules without the influence of the solvent.Recently, Duncan and his co-workers and Preiser and his co-workers reported the photofragmentation processes of metal ion—benzene complexes. 8· 9 Armentrout and co-workers determined the binding energy of a metal ion—benzene complex in their collision-induced fragmentationexperiments. 10 Most of