Unique Synthetic Approach toward a Phosphaalkene: Synthesis of a Selenium-substituted Phosphaalkene with Bulky Substituents
Unique Synthetic Approach toward a Phosphaalkene: Synthesis of a Selenium-substituted Phosphaalkene with Bulky Substituents
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DOI：
10.1246/cl.130862
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发表时间：
2014-01
影响因子：
1.6
通讯作者：
Koh Sugamata;T. Sasamori;N. Tokitoh
中科院分区：
文献类型：
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作者：
Koh Sugamata;T. Sasamori;N. Tokitoh
采用（Me3Si）2C=PCl(3)与TrpSeLi的取代反应和TsiP(Cl)SeTrp的处理两种方法合成了一种硒取代的磷酸烯烃（Me3Si）2C=PSeTrp （1， Trp: 9-三甲酰基）。
A selenium-substituted phosphaalkene, (Me3Si)2C=PSeTrp (1, Trp: 9-triptycyl), was synthesized by two methods, substitution reaction of (Me3Si)2C=PCl (3) with TrpSeLi, and treatment of TsiP(Cl)SeTrp...