Carbon Monoxide Addition to Ruthenium-Dithiolene Complex and Polysiloxane Hybrid Film Formation
Carbon Monoxide Addition to Ruthenium-Dithiolene Complex and Polysiloxane Hybrid Film Formation
复制标题
一氧化碳加成到钌-二硫醇络合物和聚硅氧烷杂化膜的形成
DOI：
10.1002/asia.201500617
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发表时间：
2015
影响因子：
4.1
通讯作者：
Takahiro Gunji
中科院分区：
文献类型：
--
作者：
Satoru Tsukada;Takuya Sagawa;Takahiro Gunji
研究了将一氧化碳加成到 [(η6-C6Me6)Ru(S2C6H4)] (1) 的钌中心。 [(η6-C6Me6)Ru(CO)(S2C6H4)] (2) 是通过将 CO 气体加成到溶液和固态 1 的钌中心而获得的。1 通过用氧化剂处理 2 来再现。还制备了A1/聚硅氧烷自支撑杂化膜，并且在聚硅氧烷杂化膜中1到2的转变时显示出显着的颜色变化。
The addition of carbon monoxide to the ruthenium center of [(η6‐C6Me6)Ru(S2C6H4)] (1) has been investigated. [(η6‐C6Me6)Ru(CO)(S2C6H4)] (2) was obtained by the addition of CO gas to the ruthenium center of1in both solution and solid states.1was reproduced by treating2with an oxidant. A1/polysiloxane self‐standing hybrid film was also prepared and showed a dramatic color change upon transformation of1to2in polysiloxane hybrid film.