Aluminum chlorohydrate I: Structure studies.
Aluminum chlorohydrate I: Structure studies.
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DOI：
10.1002/jps.2600700711
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发表时间：
1981-07
影响因子：
3.8
通讯作者：
D. Teagarden;J. Kozlowski;Joe L. White;S. Hem
中科院分区：
文献类型：
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作者：
D. Teagarden;J. Kozlowski;Joe L. White;S. Hem
x射线衍射、IR和27AI-NMR谱分析表明，水合氯铝是由一个四面体结构的中心铝和12个八面体结构的铝原子组成的。配合物AI13O4(OH)24(H2O)7+12本质上是球形的，+7电荷均匀地分布在表面。7个氯离子作为反离子与络合物结合。这种结构与合成方法和提出的止汗活性机制一致。
X-ray diffraction and IR and 27AI-NMR spectroscopy indicate that aluminum chlorohydrate is composed of a central aluminum in a tetrahedral configuration surrounded by 12 aluminum atoms in octahedral configuration. The complex, AI13O4(OH)24(H2O)7+12, is essentially spherical, with the +7 charge equally distributed on the surface. Seven chloride ions are associated with the complex as counterions. This structure is consistent with both the method of synthesis and the proposed mechanism of antiperspirant activity.