Reversed micelle of dodecylpyridinium iodide in benzene. Pressure-jump relaxation kinetic and equilibrium study of the solubilization of 7,7,8,8-tetracyanoquinodimethane
Reversed micelle of dodecylpyridinium iodide in benzene. Pressure-jump relaxation kinetic and equilibrium study of the solubilization of 7,7,8,8-tetracyanoquinodimethane
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十二烷基碘化吡啶在苯中的反胶束。
DOI：
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发表时间：
1982
期刊：
影响因子：
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通讯作者：
Z. A. Schelly
中科院分区：
文献类型：
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作者：
S. Harada;Z. A. Schelly
讨论了干苯（含 0.03% w/w 水）中十二烷基碘化吡啶反转胶束的蒸气压渗透压结果，从而得出系统的平衡描述。该信息又与分光光度结果一起用于解释胶束溶解 7,7,8,8-四氰基对醌二甲烷的压力跳跃动力学。讨论了增溶机制的细节，并报告了平衡浓度、速率和平衡常数以及增溶活化能的数值。 20 篇参考文献。
Vapor pressure osmometric results on dodecylpyridinium iodide reversed micelle in dry benzene (containing 0.03% w/w water), which lead to an equilibrium description of the system, are discussed. This information in turn, together with spectrophotometric results, is used for the interpretation of the pressure-jump kinetics of the solubilization of 7,7,8,8-tetracyanoquinodimethane by the micelle. Details of the solubilization mechanism are discussed, and numeric values of equilibrium concentrations, rate and equilibrium constants, and the activation energy of solubilization are reported. 20 references.