Molecular beam studies of gas-liquid interfaces.

Molecular beam studies of gas-liquid interfaces.
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气液界面的分子束研究。

DOI:
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发表时间:
2004
期刊:
Annual review of physical chemistry (Print)
影响因子:
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通讯作者:
G. Nathanson
G. Nathanson
中科院分区:
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文献类型:
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作者:
G. Nathanson

文献摘要

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分子束散射实验提供了一种方法来解开气体和液体之间的能量转移和化学反应所涉及的基本步骤。在回顾了这一领域的历史和最新进展后,我们回顾了气-液碰撞的运动学研究,以及HCl,DCl和HBr与过冷硫酸和液体甘油的质子交换。这些实验有助于澄清在控制捕获和界面和体相反应的表面区域的作用。
Molecular beam scattering experiments provide a way to disentangle the elementary steps involved in energy transfer and chemical reactions between gases and liquids. After surveying the history and recent progress in this field, we review studies of the kinematics of gas-liquid collisions and proton exchange of HCl, DCl, and HBr with supercooled sulfuric acid and liquid glycerol. These experiments help to clarify the role of the surface region in controlling trapping and interfacial- and bulk-phase reactions.