KINETIC ASPECTS OF ELECTROCHEMISTRY OF DISPERSE SYSTEMS .2. INDUCED DIPOLE-MOMENT AND THE NONEQUILIBRIUM DOUBLE-LAYER OF A COLLOID PARTICLE
KINETIC ASPECTS OF ELECTROCHEMISTRY OF DISPERSE SYSTEMS .2. INDUCED DIPOLE-MOMENT AND THE NONEQUILIBRIUM DOUBLE-LAYER OF A COLLOID PARTICLE
复制标题
DOI：
10.1016/0001-8686(80)87005-9
复制
发表时间：
1980-01-01
影响因子：
15.6
通讯作者：
SHILOV, VN
中科院分区：
文献类型：
--
作者：
DUKHIN, SS;SHILOV, VN
(1)由于偶极子场和单位电荷场在介电介质中以ce的倍数减小，故d为f。因此，由于介电屏蔽的作用，有效偶极矩比真实偶极矩d= defe小一个系数ce。Z)，占据一定体积V的任何复杂电荷系统，在大大超过该体积的线性尺寸的距离上的势分布，可以用与eq_l_相同的公式表示
(1) d ef because the dipole field as well as the unit charge field decreases in the dielectric medium by a factor of ce. Therefore, the effective dipole moment is, by a factor of ce, smaller than the true dipole moment d= def-ce due to dielectric screening-According to the we77 known theorem of electrostatics(ref. Z), the potential distribution of any complex system of charges occupying a certain volume V, at a distance which considerably exceeds the linear sizes of this volume, is expressed by the same formula as in Eq_ l_ This similarity permits introduction of the