Dynamic Quantum Molecular Sieving Separation of D2 from H2-D2 Mixture with Nanoporous Materials
Dynamic Quantum Molecular Sieving Separation of D2 from H2-D2 Mixture with Nanoporous Materials
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DOI：
10.1021/ja305809u
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发表时间：
2012-11-14
影响因子：
15
通讯作者：
Kaneko, Katsumi
中科院分区：
文献类型：
--
作者：
Niimura, Subaru;Fujimori, Toshihiko;Kaneko, Katsumi
使用流动法在 77 K 下测量活性碳纤维、碳分子筛、沸石和单壁碳纳米管的 D-2 与 H-2-D-2 混合物的量子分子筛分离性。所有样品中 D-2 的吸附量均明显大于 H-2。对于沸石 (MS13X)，D-2 和 H-2 之间的最大吸附率差异为 40%，D-2 相对于 H2 的选择性为 3.05。
Quantum molecular sieving separability of D-2 from an H-2-D-2 mixture was measured at 77 K for activated carbon fiber, carbon molecular sieve, zeolite and single wall carbon nanotube using a flow method. The amount of adsorbed D-2 was evidently larger than H-2 for all samples. The maximum adsorption ratio difference between D-2 and H-2 was 40% for zeolite (MS13X), yielding a selectivity for D-2 with respect to H2 of 3.05.