Dual-responsive inverse opal films based on a crosslinked liquid crystal polymer containing azobenzene

Dual-responsive inverse opal films based on a crosslinked liquid crystal polymer containing azobenzene
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基于含偶氮苯的交联液晶聚合物的双响应反蛋白石薄膜

DOI:
10.1039/c4tc01825g
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发表时间:
2014-11
影响因子:
6.4
通讯作者:
Yanlei Yu
Yanlei Yu
中科院分区:
材料科学2区
文献类型:
--
作者:
Yuyun Liu;Yanlei Yu;Yanlei Yu;Yanlei Yu

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以含偶氮苯的交联液晶聚合物(CLCP)为基材,制备了新型光热双响应反蛋白石薄膜。在CLCP发生变形的同时,光或温度也会引起反蛋白石薄膜反射光谱的切换行为。我们发现CLCP的热相变和光致相变使其光学性能急剧下降。热致反蛋白石膜的下降幅度远大于光致反蛋白石膜。
Novel photo and thermal dual-responsive inverse opal films were fabricated based on a crosslinked liquid crystal polymer (CLCP) containing azobenzene. Accompanying the deformation of the CLCP, switchable behavior on the reflection spectra of the inverse opal film was induced by light or temperature. We found that the optical properties were drastically decreased by thermal or photoinduced phase transitions of the CLCP. It was also found that the extent of decrease in the heat-induced inverse opal film is much more than in the one induced by light.
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