Structural determination of AMgNi4 (where A=Ca, La, Ce, Pr, Nd and Y) in the AuBe5 type structure

Structural determination of AMgNi4 (where A=Ca, La, Ce, Pr, Nd and Y) in the AuBe5 type structure
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DOI:
10.1016/s0925-8388(02)00323-7
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发表时间:
2002-10-28
影响因子:
6.2
通讯作者:
Yamashita, I
Yamashita, I
中科院分区:
材料科学2区
文献类型:
--
作者:
Kadir, K;Noréus, D;Yamashita, I

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采用原子比为A:Mg:Ni = 1:1:4的方法直接合成了多种新型三元镁基合金AMgNi(4)(其中A = Ca, La, Ce, Pr, Nd, Y)。用ginier - hagg x射线粉末衍射测定了晶体结构。该化合物具有立方SnMgCu4 (AuBe5型)结构,与(C-15) MgCu2结构相关。所有的原子间距离都表示金属型成键。(C) 2002 Elsevier Science B.V.版权所有
A number of new ternary magnesium based alloys AMgNi(4) (where A = Ca, La, Ce, Pr, Nd, and Y) have been synthesized by direct combination of the elements in the atomic ratio A:Mg:Ni = 1:1:4. The crystal structures were determined by Guinier-Hagg X-ray powder diffraction. The compounds have a cubic SnMgCu4 (AuBe5 type) structure, which is related to the (C-15) MgCu2 structure. All interatomic distances indicate metallic-type bonding. (C) 2002 Elsevier Science B.V. All rights reserved.