Space charge trapping in electrical potential well caused by permanent and induced dipoles for LDPE/MgO nanocomposite
Space charge trapping in electrical potential well caused by permanent and induced dipoles for LDPE/MgO nanocomposite
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DOI：
10.1109/t-dei.2008.4446746
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发表时间：
2008-02-01
影响因子：
3.1
通讯作者：
Okamoto, Tatsuki
中科院分区：
文献类型：
--
作者：
Takada, Tatsuo;Hayase, Yuji;Okamoto, Tatsuki
Space charge accumulation in low-density polyethylene film containing a small amount of MgO nanoparticles (LDPE/MgO nanocomposite film) subjected to an electric field greater than 100 kV/mm has been studied using an improved pulsed electroacoustic (PEA) system. No marked space charge accumulation was observed in LDPE/MgO nanocomposite films. To determine the mechanism of no space charge accumulation in the LDPE/MgO nanocomposite film, we compared electric potential wells produced by a permanent dipole moment such as that of carbonyl groups (C=O) and an induced dipole consisting of MgO nanoparticles (spherical dielectrics) under a high electric field to create a trapping site for electric charge carriers. The trapping depth created by the permanent dipole moment such as that of the carbonyl groups (C=O) of chemical defects is approximately 0.45 eV. However, the potential well induced by high-permittivity dielectric nanoparticles (MgO) is about 1.5 to 5.0 eV, which is much deeper than that induced by chemical defects. The suppression of space charge formation is explained using the potential well model consisting of a dipole induced by a high-permittivity dielectric nanoparticle. We explained the suppression mechanism of charge accumulation in the LDPE/MgO film that contains deep traps.
